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INTERNATIONAL JOURNAL OF NOVEL RESEARCH AND DEVELOPMENT International Peer Reviewed & Refereed Journals, Open Access Journal ISSN Approved Journal No: 2456-4184 | Impact factor: 8.76 | ESTD Year: 2016 Scholarly open access journals, Peer-reviewed, and Refereed Journals, Impact factor 8.76 (Calculate by google scholar and Semantic Scholar | AI-Powered Research Tool) , Multidisciplinary, Monthly, Indexing in all major database & Metadata, Citation Generator, Digital Object Identifier(DOI) |
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| Paper Title: | Diverse reactivity of (N, N, N) tridentate bis-2,2’-(N-benzylamino) azobenzene, ligands with Na2PdCl4 and K2PtCl4 |
| Authors Name: | Paritosh Mandal |
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| Author Reg. ID: |
IJNRD_182711
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| Published Paper Id: | IJNRD2208175 |
| Published In: | Volume 7 Issue 8, August-2022 |
| DOI: | |
| Abstract: | The newly designed tridentate ligand, bis-2,2'-(N-benzylamino)azobenzene (2), has been prepared by the reaction between 2,2'-diaminoazobenzene (1) and benzyl chloride in the presence of K2CO3. The reaction of these ligands with Na2PdCl4 and K2PtCl4 separately in a 1:1 ratio in methanol afforded two structurally diverse Pd(II) and Pt(II) complexes (3 & 4). The reaction of the N-benzylated azo ligand (2) gives a new cyclopalladated Pd (II) amido azo complex (3). However, when this ligand reacts with platinum salt, it affords an unprecedented ortho-platinated azo-imine complex (4). All three complexes were characterized by 1H NMR, UV-vis, FT-IR spectroscopy, and elemental analysis. Furthermore, the solid-state structures of azo-amido Pd(II) (3) and ortho-platinated azo-imine complex (4) were determined using single crystal X-ray diffraction analysis, and it revealed that the bis-2,2'-(N-benzylamino)azobenzene ligand binds with the Pd(II) ion center in a monoanionic tridentate (N, N, N) fashion, offering a distorted square planar geometry where the fourth coordination site is satisfied by one chloride ligand. In contrast, ligand (2) binds to Pt(II) in a bi-anionic tetra-anionic tetra-dentate (C, N, N, N) fashion, resulting in distorted square planar geometry. Furthermore, the air/moisture stable Pd(II) complex (3), with N-benzyl substituted azobenzene ligand, acts as an efficient catalyst for the Suzuki and Heck reactions under mild conditions. The electrochemical behaviors of the new ortho-platinated complex (4) were also examined. |
| Keywords: | Pd(II) & Pt(II) azo-amido complexes, ortho-platinated complex, Crystal structures, Catalytic activity, Redox property. |
| Cite Article: | "Diverse reactivity of (N, N, N) tridentate bis-2,2’-(N-benzylamino) azobenzene, ligands with Na2PdCl4 and K2PtCl4", International Journal of Novel Research and Development (www.ijnrd.org), ISSN:2456-4184, Vol.7, Issue 8, page no.1539-1544, August-2022, Available :http://www.ijnrd.org/papers/IJNRD2208175.pdf |
| Downloads: | 000118756 |
| ISSN: |
2456-4184 | IMPACT FACTOR: 8.76 Calculated By Google Scholar| ESTD YEAR: 2016 An International Scholarly Open Access Journal, Peer-Reviewed, Refereed Journal Impact Factor 8.76 Calculate by Google Scholar and Semantic Scholar | AI-Powered Research Tool, Multidisciplinary, Monthly, Multilanguage Journal Indexing in All Major Database & Metadata, Citation Generator |
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Published Paper ID:IJNRD2208175 Registration ID: 182711 Published In: Volume 7 Issue 8, August-2022 DOI (Digital Object Identifier): Page No: 1539-1544 Country: Beldanga, West Bengal, India Research Area: Chemistry Publisher : IJ Publication Published Paper URL : https://www.ijnrd.org/viewpaperforall?paper=IJNRD2208175 Published Paper PDF: https://www.ijnrd.org/papers/IJNRD2208175 |
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ISSN: 2456-4184
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